Heat expedites the process, but adds significant danger - for obvious reasons.
My bio-d partner has recently mastered soap making! Best soap I've ever used, seriously (from degreaser to shampoo!). We are working on a still to recover the methanol, but he is currently using turkey fryer to heat the glycerin and consequently boil off the methanol.
I've heard the commercial biodiesel folks make as much $$ off their glycerin as they do biodiesel... seems a shame to 'throw it away'. It can also be used by concrete people as form release - most use diesel, so there's a huge savings for them (and $$ for you). Just a couple thoughts! 
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I'm not cheap - I'm just BROKE!!
2001 F-350, DRW, 4x4, XLT Crew Cab, flat bed, 7.3, 6 spd, LSD, 4.10's NAPA 6637, Dipricol Optix gauges on pillar - EGT, Boost, Fuel Press., HPO Press. - No Muffler, AIH delete, Mobil 1 in trans, t-case & diffs, LUK clutch, Swamps single-shots!!! Vegistroke-inspired WVO system w/95,000 trouble-free miles! DP-Tuner F5 - stock-high idle-40t-60t-80e-100 - Lovin' it!! 203 t-stat w/billet housing, Evans coolant, coolant filter, boost relief valve, Dieselsite IC boots, Hella headlight harness, '07 grill/lites and big, bad front bumper!
2000 Excursion 4x4 Limited - F5, AIS, Frybrid/V3 SVO conversion that does 100mi/day. 30k flawless VO miles so far!
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