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Yes but ..........If I hook up a battery charger to the one battery under the hood, will it charge the other battery under the floor on the frame rail?
The remote battery will see the voltage at the end of its long cable so the connections on either end of that cable are doubly important. If one or both of those cable ends is compromised by corrosion the remote battery will charge more slowly and won't deliver as much fire to help get the van started. And don't neglect the grounds. The little tiny electrons need to leave the battery AND return to the battery. Anything slowing them down will affect performance of the whole system.